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White Collar

<p>&nbsp;Matthew Bomer of 'White Collar'</p>

Matthew Bomer ("Chuck") plays a master criminal.

Tim DeKay ("Tell Me You Love Me") is a dogged FBI agent.

You wouldn't think they'd get along, right?

WRONG! 

Turns out, they can join forces to fight crime in USA's new drama series "White Collar," premiering on Oct. 23. 

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