Will 'The Heat's' Sandra Bullock and Melissa McCarthy join the list?
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13. 'Kiss Kiss Bang Bang' (2005)
It was no accident that this film kicked off Robert Downey Jr's. return to Hollywood favor, and he has taken full advantage of the heat that the film generated for him. The public may not have seen the movie, but everyone in the industry did, and he was undeniable in it. You have to give some of the credit to Val Kilmer, though, who is the perfect foil for Downey as Gay Perry, and Shane Black seems to have realized early on that he had hold of something special in the chemistry between these two. Michelle Monaghan may have been Downey's love interest in the movie, but the pairing that we were rooting for was between Downey and Kilmer, pure comedy heaven.