We expect Angelina Jolie to sparkle, but who will be a fashion disaster?
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Potentially Best: Angelina Jolie
Yes, it's hard to forget her Vampira moment at the Oscars so long ago, but she's emerged as one of the women most likely to steal the spotlight for all the right reasons on every red carpet she walks. While she's only presenting at this ceremony (which suggests she'll be impeccably put together but won't attempt to steal the spotlight from nominees), we're betting on the Oscar winner to deliver yet another graceful gown.