We only got a glimpse, but that's all we really need to start guessing.
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Who she is: She’s Storm. A “goddess” of the weather, a queen of Wakanda, and a veteran member of the X-Men. Her powers include control over the damn weather and general badassery. Everyone knows who Storm is.
How she might fit: T’challa is getting his own “Black Panther” movie and Storm is the wife of the king of Wakanda. It wouldn’t be outside the realm of possibility for this “miracle” to come to the aid of the Avengers in their time of need. After all, Wakanda is a very technologically advanced country; they might be able to help stop Ultron.
Probability: 5% - I’d place this lower if Marvel hadn’t already shown a willingness to use the same mutants as Fox. Quicksilver’s double billing cracks the door for other X-Men. Dare to dream...