Cameron Crowe's Pearl Jam documentary, heading to the Toronto Film Festival this fall, is chock-full of previously unreleased tunes, mostly rarities and live cuts. Now the tracklist to the film's soundtrack has been unveiled.

The double-disc set includes highlights like "Black" from PJ's still-unreleased MTV Unplugged appearance, demo versions of songs like "It Ain't Like That" and "Need to Know" and two versions of "Nothing As It Seems."

There's also the cover of Mother Love Bone's "Crown of Thorns," which we previewed earlier this week.

"Pearl Jam Twenty" -- named for the band's 20th anniversary -- has its soundtrack drop on Sept. 20; that's the same day it heads to select theaters for one night only. It will be followed up with a full week run starting Sept. 23 in key markets.

Disc One

“Release” Verona, Italy
“Alive” Seattle, WA
“Garden” Zurich, Switzerland
“Why Go” Hamburg, Germany
“Black” MTV Unplugged
“Blood” Auckland, New Zealand
“Last Exit” Taipei, Taiwan
“Not For You” Manilla, Philippines
“Do The Evolution” Monkeywrench Radio
“Thumbing My Way” Seattle, WA
“Crown of Thorns” Las Vegas, NV
“Let Me Sleep”  - (Christmas Time) Verona, Italy
“Walk With Me” -  Mountain View, CA
“Just Breathe: -  Saturday Night Live

Disc Two

“Say Hello 2 Heaven” - Demo
“Times Of Trouble” -  Demo
“Acoustic #1”  - Demo
“It Ain’t Like That” - Demo
“Need To Know”  - Demo
“Be Like Wind” - Demo
“Given To Fly” - Instrumental
“Nothing As It Seems” - Demo
“Nothing As It Seems” - Seattle, WA
“Indifference” - Bologna, Italy
“Of The Girl” - Instrumental
“Faithfull” - Pistoia, Italy
“Bu$hleaguer” - Uniondale, NY
“Betterman” - New York, NY
“Rearviewmirror” - Los Angeles, CA