Plus: The Wasp, The Vision, Thanos and more
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Real Name: None (although at one point he adopted the name Jonas)
First Appearance: The Avengers No. 57 (October, 1968)
Powers: Created by Ultron, the Vision is a super-advanced android that can fly, phase, regenerate and fire destructive optical energy beams.
Hero or Villain: Originally created as a weapon to fight the Avengers, the Vision was eventually convinced to turn against his maker and join the team, although his android nature makes him vulnerable to being controlled by outside forces from time to time.
Why: The Vision could be initially set up as an adversary, before joining the team in subsequent Marvel movies. And, frankly, he's just plain cool.